grain, in metallurgy, any of the crystallites (small crystals or grains) of varying, randomly distributed, small sizes that compose a solid metal. Randomly oriented, the grains contact each other at surfaces called grain boundaries. The structure and size of the grains determine important physical properties of the solid metal. Grains of a metal ingot can be elongated and locked together by rolling to improve the mechanical properties in the direction of grain length. Internal stresses at grain boundaries may be relieved by annealing to restore exhausted ductility in certain alloys or to harden other alloys.