The constitution of the nucleus was poorly understood at the time because the only known particles were the electron and the proton. It had been established that nuclei are typically about twice as heavy as can be accounted for by protons alone. A consistent theory was impossible until English physicist James Chadwick discovered the neutron in 1932. He found that alpha particles reacted with beryllium nuclei to eject neutral particles with nearly the same mass as protons. Almost all nuclear phenomena can be understood in terms of a nucleus composed of neutrons and protons. Surprisingly, the neutrons and protons in the nucleus move to a large extent in orbitals as though their wave functions were independent of one another. Each neutron or proton orbital is described by a stationary wave pattern with peaks and nodes and angular momentum quantum numbers. The theory of the nucleus based on these orbitals is called the shell nuclear model. It was introduced independently in 1948 by Maria Goeppert Mayer of the United States and Johannes Hans Daniel Jensen of West Germany, and it developed in succeeding decades into a comprehensive theory of the nucleus.

The interactions of neutrons with nuclei had been studied during the mid-1930s by Italian-born American physicist Enrico Fermi and others. Nuclei readily capture neutrons, which, unlike protons or alpha particles, are not repelled from the nucleus by a positive charge. When a neutron is captured, the new nucleus has one higher unit of atomic mass. If a nearby isotope of that atomic mass is more stable, the new nucleus will be radioactive, convert the neutron to a proton, and assume the more-stable form.

Nuclear fission was discovered by German chemists Otto Hahn and Fritz Strassmann in 1938 during the course of experiments initiated and explained by Austrian physicist Lise Meitner. In fission a uranium nucleus captures a neutron and gains enough energy to trigger the inherent instability of the nucleus, which splits into two lighter nuclei of roughly equal size. The fission process releases more neutrons, which can be used to produce further fissions. The first nuclear reactor, a device designed to permit controlled fission chain reactions, was constructed at the University of Chicago under Fermi’s direction, and the first self-sustaining chain reaction was achieved in this reactor in 1942. In 1945 American scientists produced the first fission bomb, also called an atomic bomb, which used uncontrolled fission reactions in either uranium or the artificial element plutonium. In 1952 American scientists used a fission explosion to ignite a fusion reaction in which isotopes of hydrogen combined thermally into heavier helium nuclei. This was the first thermonuclear bomb, also called an H-bomb, a weapon that can release hundreds or thousands of times more energy than a fission bomb.

Quantum field theory and the standard model

Dirac not only proposed the relativistic equation for the electron but also initiated the relativistic treatment of interactions between particles known as quantum field theory. The theory allows particles to be created and destroyed and requires only the presence of suitable interactions carrying sufficient energy. Quantum field theory also stipulates that the interactions can extend over a distance only if there is a particle, or field quantum, to carry the force. The electromagnetic force, which can operate over long distances, is carried by the photon, the quantum of light. Because the theory allows particles to interact with their own field quanta, mathematical difficulties arose in applying the theory.

The theoretical impasse was broken as a result of a measurement carried out in 1946 and 1947 by American physicist Willis Eugene Lamb, Jr. Using microwave techniques developed during World War II, he showed that the hydrogen spectrum is actually about one-tenth of one percent different from Dirac’s theoretical picture. Later, German-born American physicist Polykarp Kusch found a similar anomaly in the size of the magnetic moment of the electron. Lamb’s results were announced at a famous Shelter Island Conference held in the United States in 1947. German-born American physicist Hans Bethe and others realized that the so-called Lamb shift was probably caused by electrons and field quanta that may be created from the vacuum. The previous mathematical difficulties were overcome by Richard Feynman, Julian Schwinger, and Tomonaga Shin’ichirō, who shared the 1965 Nobel Prize for Physics, and Freeman Dyson, who showed that their various approaches were mathematically identical. The new theory, called quantum electrodynamics, was found to explain all the measurements to very high precision. Apparently, quantum electrodynamics provides a complete theory of how electrons behave under electromagnetism.

Beginning in the 1960s, similarities were found between the weak force and electromagnetism. Sheldon Glashow, Abdus Salam, and Steven Weinberg combined the two forces in the electroweak theory, for which they shared the Nobel Prize for Physics in 1979. In addition to the photon, three field quanta were also predicted as additional force carriers—the W particle, the Z particle, and the Higgs boson. The W and Z particles were carriers of the weak force, and the Higgs boson was the carrier of the Higgs field, which leads to the W and Z particles being heavy and the photon having a mass of zero. The discoveries of the W and Z particles in 1983, with correctly predicted masses, established the validity of the electroweak theory. A particle that was likely the Higgs boson was finally detected in 2012.

In all, hundreds of subatomic particles have been discovered since the first unstable particle, the muon, was identified in cosmic rays in the 1930s. By the 1960s patterns emerged in the properties and relationships among subatomic particles that led to the quark theory. Combining the electroweak theory and the quark theory, a theoretical framework called the Standard Model was constructed; it includes all known particles and field quanta. In the Standard Model there are two broad categories of particles, the leptons and the quarks. Leptons include electrons, muons, and neutrinos, and, aside from gravity, they interact only with the electroweak force.

The quarks are subject to the strong force, and they combine in various ways to make bound states. The bound quark states, called hadrons, include the neutron and the proton. Three quarks combine to form a proton, a neutron, or any of the massive hadrons known as baryons. A quark combines with an antiquark to form mesons such as the pion. Quarks have never been observed, and physicists do not expect to find one. The strength of the strong force is so great that quarks cannot be separated from each other outside hadrons. The existence of quarks has been confirmed indirectly in several ways, however. In experiments conducted with high-energy electron accelerators starting in 1967, physicists observed that some of the electrons bombarded onto proton targets were deflected at large angles. As in Rutherford’s gold-foil experiment, the large-angle deflection implies that hadrons have an internal structure containing very small charged objects. The small objects are presumed to be quarks. To accommodate quarks and their peculiar properties, physicists developed a new quantum field theory, known as quantum chromodynamics, during the mid-1970s. This theory explains qualitatively the confinement of quarks to hadrons. Physicists believe that the theory should explain all aspects of hadrons. However, mathematical difficulties in dealing with the strong interactions in quantum chromodynamics are more severe than those of quantum electrodynamics, and rigorous calculations of hadron properties have not been possible. Nevertheless, numerical calculations using the largest computers seem to confirm the validity of the theory.

George F. Bertsch Sharon Bertsch McGrayne

subatomic particle, any of various self-contained units of matter or energy that are the fundamental constituents of all matter. Subatomic particles include electrons, the negatively charged, almost massless particles that nevertheless account for most of the size of the atom, and they include the heavier building blocks of the small but very dense nucleus of the atom, the positively charged protons and the electrically neutral neutrons. But these basic atomic components are by no means the only known subatomic particles. Protons and neutrons, for instance, are themselves made up of elementary particles called quarks, and the electron is only one member of a class of elementary particles that also includes the muon and the neutrino. More-unusual subatomic particles—such as the positron, the antimatter counterpart of the electron—have been detected and characterized in cosmic ray interactions in Earth’s atmosphere. The field of subatomic particles has expanded dramatically with the construction of powerful particle accelerators to study high-energy collisions of electrons, protons, and other particles with matter. As particles collide at high energy, the collision energy becomes available for the creation of subatomic particles such as mesons and hyperons. Finally, completing the revolution that began in the early 20th century with theories of the equivalence of matter and energy, the study of subatomic particles has been transformed by the discovery that the actions of forces are due to the exchange of “force” particles such as photons and gluons. More than 200 subatomic particles have been detected—most of them highly unstable, existing for less than a millionth of a second—as a result of collisions produced in cosmic ray reactions or particle accelerator experiments. Theoretical and experimental research in particle physics, the study of subatomic particles and their properties, has given scientists a clearer understanding of the nature of matter and energy and of the origin of the universe.

The current understanding of the state of particle physics is integrated within a conceptual framework known as the Standard Model. The Standard Model provides a classification scheme for all the known subatomic particles based on theoretical descriptions of the basic forces of matter.

Basic concepts of particle physics

The divisible atom

The physical study of subatomic particles became possible only during the 20th century, with the development of increasingly sophisticated apparatuses to probe matter at scales of 10−15 metre and less (that is, at distances comparable to the diameter of the proton or neutron). Yet the basic philosophy of the subject now known as particle physics dates to at least 500 bce, when the Greek philosopher Leucippus and his pupil Democritus put forward the notion that matter consists of invisibly small, indivisible particles, which they called atoms. For more than 2,000 years the idea of atoms lay largely neglected, while the opposing view that matter consists of four elements—earth, fire, air, and water—held sway. But by the beginning of the 19th century the atomic theory of matter had returned to favour, strengthened in particular by the work of John Dalton, an English chemist whose studies suggested that each chemical element consists of its own unique kind of atom. As such, Dalton’s atoms are still the atoms of modern physics. By the close of the century, however, the first indications began to emerge that atoms are not indivisible, as Leucippus and Democritus had imagined, but that they instead contain smaller particles.

In 1896 the French physicist Henri Becquerel discovered radioactivity, and in the following year J.J. Thomson, a professor of physics at the University of Cambridge in England, demonstrated the existence of tiny particles much smaller in mass than hydrogen, the lightest atom. Thomson had discovered the first subatomic particle, the electron. Six years later Ernest Rutherford and Frederick Soddy, working at McGill University in Montreal, found that radioactivity occurs when atoms of one type transmute into those of another kind. The idea of atoms as immutable, indivisible objects had become untenable.

The basic structure of the atom became apparent in 1911, when Rutherford showed that most of the mass of an atom lies concentrated at its centre, in a tiny nucleus. Rutherford postulated that the atom resembled a miniature solar system, with light, negatively charged electrons orbiting the dense, positively charged nucleus, just as the planets orbit the Sun. The Danish theorist Niels Bohr refined this model in 1913 by incorporating the new ideas of quantization that had been developed by the German physicist Max Planck at the turn of the century. Planck had theorized that electromagnetic radiation, such as light, occurs in discrete bundles, or “quanta,” of energy now known as photons. Bohr postulated that electrons circled the nucleus in orbits of fixed size and energy and that an electron could jump from one orbit to another only by emitting or absorbing specific quanta of energy. By thus incorporating quantization into his theory of the atom, Bohr introduced one of the basic elements of modern particle physics and prompted wider acceptance of quantization to explain atomic and subatomic phenomena.

Periodic Table of the elements concept image (chemistry)
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Size

Subatomic particles play two vital roles in the structure of matter. They are both the basic building blocks of the universe and the mortar that binds the blocks. Although the particles that fulfill these different roles are of two distinct types, they do share some common characteristics, foremost of which is size.

The small size of subatomic particles is perhaps most convincingly expressed not by stating their absolute units of measure but by comparing them with the complex particles of which they are a part. An atom, for instance, is typically 10−10 metre across, yet almost all of the size of the atom is unoccupied “empty” space available to the point-charge electrons surrounding the nucleus. The distance across an atomic nucleus of average size is roughly 10−14 metre—only 1/10,000 the diameter of the atom. The nucleus, in turn, is made up of positively charged protons and electrically neutral neutrons, collectively referred to as nucleons, and a single nucleon has a diameter of about 10−15 metre—that is, about 1/10 that of the nucleus and 1/100,000 that of the atom. (The distance across the nucleon, 10−15 metre, is known as a fermi, in honour of the Italian-born physicist Enrico Fermi, who did much experimental and theoretical work on the nature of the nucleus and its contents.)

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The sizes of atoms, nuclei, and nucleons are measured by firing a beam of electrons at an appropriate target. The higher the energy of the electrons, the farther they penetrate before being deflected by the electric charges within the atom. For example, a beam with an energy of a few hundred electron volts (eV) scatters from the electrons in a target atom. The way in which the beam is scattered (electron scattering) can then be studied to determine the general distribution of the atomic electrons.

At energies of a few hundred megaelectron volts (MeV; 106 eV), electrons in the beam are little affected by atomic electrons; instead, they penetrate the atom and are scattered by the positive nucleus. Therefore, if such a beam is fired at liquid hydrogen, whose atoms contain only single protons in their nuclei, the pattern of scattered electrons reveals the size of the proton. At energies greater than a gigaelectron volt (GeV; 109 eV), the electrons penetrate within the protons and neutrons, and their scattering patterns reveal an inner structure. Thus, protons and neutrons are no more indivisible than atoms are; indeed, they contain still smaller particles, which are called quarks.

Quarks are as small as or smaller than physicists can measure. In experiments at very high energies, equivalent to probing protons in a target with electrons accelerated to nearly 50,000 GeV, quarks appear to behave as points in space, with no measurable size; they must therefore be smaller than 10−18 metre, or less than 1/1,000 the size of the individual nucleons they form. Similar experiments show that electrons too are smaller than it is possible to measure.