high-Tc superconductor

physics
Also known as: high-transitional temperature superconductor, higher-temperature superconductor

Learn about this topic in these articles:

ceramics

  • Figure 1: Schematic diagram of a zirconia oxygen sensor used to monitor automobile exhaust gases. The sensor, approximately the size of a spark plug, is fitted into the exhaust manifold of an automobile engine. The thimble-shaped zirconia sensor, sandwiched between thin layers of porous platinum, is exposed on its interior to outside air and on its exterior to exhaust gas passing through slits in the sensor shield. The two platinum surfaces serve as electrodes, conducting a voltage across the zirconia that varies according to the difference in oxygen content between the exhaust gas and the outside air.
    In conductive ceramics: Superconductors

    …ceramic conductors are the so-called high Tc superconductors, materials that lose their resistance at much higher critical temperatures than their metal alloy counterparts. Most high Tc ceramics are layered structures, with two-dimensional copper-oxygen sheets along which superconduction takes place. The first of these was discovered in 1986 by the Swiss…

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  • In electroceramics

    …are referred to as high-Tc superconductors.

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superconductivity

  • Figure 1: Specific heat in the normal (Cen) and superconducting (Ces) states of a classic superconductor as a function of absolute temperature. The two functions are identical at the transition temperature (Tc) and above Tc.
    In superconductivity: Thermal properties of superconductors

    …been found to have extraordinarily high transition temperatures, denoted Tc. This is the temperature below which a substance is superconducting. The properties of these high-Tc compounds are different in some respects from those of the types of superconductors known prior to 1986, which will be referred to as classic superconductors…

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  • Figure 1: Specific heat in the normal (Cen) and superconducting (Ces) states of a classic superconductor as a function of absolute temperature. The two functions are identical at the transition temperature (Tc) and above Tc.
    In superconductivity: Higher-temperature superconductivity

    Ever since Kamerlingh Onnes discovered that mercury becomes superconducting at temperatures less than 4 K, scientists have been searching for superconducting materials with higher transition temperatures. Until 1986 a compound of niobium and germanium (Nb3Ge) had

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Key People:
Brian D. Josephson

Josephson effect, flow of electric current between two pieces of superconducting material separated by a thin layer of insulating material. Superconductors are materials that lose all electrical resistance when cooled below a certain temperature near absolute zero. The English physicist Brian D. Josephson predicted the flow of current in 1962 on the basis of the BCS theory (q.v.) of superconductivity. The subsequent experimental verification of the Josephson effect lent support to the BCS theory.

The Josephson current flows only if no battery is connected across the two superconductors. If a battery is inserted, the current oscillates very rapidly so that no net current flows. The presence of magnetic fields near the superconductors influences the Josephson effect, allowing it to be used to measure very weak magnetic fields.

According to the BCS theory, superconductivity is a result of the correlated motion of electrons in the superconducting solid. Part of this correlation is the formation of pairs of electrons called Cooper pairs. According to Josephson, under certain circumstances these Cooper pairs move from one superconductor to the other across the thin insulating layer. Such motion of pairs of electrons constitutes the Josephson current, and the process by which the pairs cross the insulating layer is called Josephson tunneling.

The Josephson effect is central to the operation of the superconducting quantum interference device (SQUID), which is a very sensitive detector of magnetic fields. It is used to measure tiny variations in the magnetic field of the Earth and also of the human body.

This article was most recently revised and updated by William L. Hosch.