resin, any natural or synthetic organic compound consisting of a noncrystalline or viscous liquid substance. Natural resins are typically fusible and flammable organic substances that are transparent or translucent and are yellowish to brown in colour. They are formed in plant secretions and are soluble in various organic liquids but not in water. Synthetic resins comprise a large class of synthetic products that have some of the physical properties of natural resins but are different chemically. Synthetic resins are not clearly differentiated from plastics.

Most natural resins are exuded from trees, especially pines and firs. Resin formation occurs as a result of injury to the bark from wind, fire, lightning, or other cause. The fluid secretion ordinarily loses some of its more volatile components by evaporation, leaving a soft residue at first readily soluble but becoming insoluble as it ages. The ancient Chinese, Japanese, Egyptians, and others used resins in preparation of lacquers and varnishes.

Natural resins may be classified as spirit-soluble and oil-soluble. Among the former are balsams, long popular as a healing agent; turpentines used as solvents; and mastics, dragon’s blood, dammar, sandarac, and the lacs, all used as components of varnishes. The oil-soluble resins include rosin, derived along with turpentine from the long-leaf pine and long used for a variety of applications, including soapmaking; copals, used in varnishes; amber, the hardest natural resin, fabricated into jewelry; Oriental lacquer, derived from a tree native to China; and cashew-nutshell oil, derived from cashew nuts.

In modern industry natural resins have been almost entirely replaced by synthetic resins, which are divided into two classes, thermoplastic resins, which remain plastic after heat treatment, and thermosetting resins, which become insoluble and infusible on heating.

This article was most recently revised and updated by Amy Tikkanen.
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polymer, any of a class of natural or synthetic substances composed of very large molecules, called macromolecules, that are multiples of simpler chemical units called monomers. Polymers make up many of the materials in living organisms, including, for example, proteins, cellulose, and nucleic acids. Moreover, they constitute the basis of such minerals as diamond, quartz, and feldspar and such man-made materials as concrete, glass, paper, plastics, and rubbers.

The word polymer designates an unspecified number of monomer units. When the number of monomers is very large, the compound is sometimes called a high polymer. Polymers are not restricted to monomers of the same chemical composition or molecular weight and structure. Some natural polymers are composed of one kind of monomer. Most natural and synthetic polymers, however, are made up of two or more different types of monomers; such polymers are known as copolymers.

Natural polymers: organic and inorganic

Organic polymers play a crucial role in living things, providing basic structural materials and participating in vital life processes. For example, the solid parts of all plants are made up of polymers. These include cellulose, lignin, and various resins. Cellulose is a polysaccharide, a polymer that is composed of sugar molecules. Lignin consists of a complicated three-dimensional network of polymers. Wood resins are polymers of a simple hydrocarbon, isoprene. Another familiar isoprene polymer is rubber.

Other important natural polymers include the proteins, which are polymers of amino acids, and the nucleic acids, which are polymers of nucleotides—complex molecules composed of nitrogen-containing bases, sugars, and phosphoric acid. The nucleic acids carry genetic information in the cell. Starches, important sources of food energy derived from plants, are natural polymers composed of glucose.

Many inorganic polymers also are found in nature, including diamond and graphite. Both are composed of carbon. In diamond, carbon atoms are linked in a three-dimensional network that gives the material its hardness. In graphite, used as a lubricant and in pencil “leads,” the carbon atoms link in planes that can slide across one another.