hafnium, Metallic chemical element, one of the transition elements, chemical symbol Hf, atomic number 72. A ductile metal with a brilliant silvery lustre, it was discovered in 1923 in Copenhagen, Den., and given a name derived from the Latin name of that city. Hafnium has high corrosion resistance. Because of its high neutron-capture cross section and its excellent mechanical properties, hafnium is used for fabricating nuclear-control rods.