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pigment

carmine, red or purplish-red pigment obtained from cochineal (q.v.), a red dyestuff extracted from the dried bodies of certain female scale insects native to tropical and subtropical America. Carmine was used extensively for watercolours and fine coach-body colours before the advent of synthetic colouring materials. Since then it has been used only when a natural pigment is required: for pastries, confections, cosmetics, water-soluble drug preparations, and histologic stains.

To prepare carmine, the powdered insect bodies are boiled in ammonia or sodium carbonate solution, the insoluble matter is removed by filtering, and alum is added to the clear salt solution of carminic acid to precipitate the red aluminum salt. Purity of colour is ensured by the absence of iron. Stannous chloride, citric acid, borax, or gelatin may be added to regulate the formation of the precipitate. For purple shades, lime is added to the alum. Chemically, carminic acid is a complex anthraquinone derivative.

Related Topics:
dye

cochineal, red dyestuff consisting of the dried, pulverized bodies of certain female scale insects, Dactylopius coccus, of the Coccidae family, cactus-eating insects native to tropical and subtropical America. Cochineal is used to produce scarlet, crimson, orange, and other tints and to prepare pigments such as lake and carmine (qq.v.). The dye was introduced into Europe from Mexico, where it had been used long before the coming of the Spaniards.

Cochineal has been replaced almost entirely by synthetic dyes, but it continues to be used principally as a colouring agent in cosmetics and beverages. Its dyeing power is attributed to cochinealin, or carminic acid, obtained by boiling cochineal in water. Cochineal also contains glyceryl myristate (a fat) and coccerin (cochineal wax).

The insects are carefully brushed from the cacti into bags and are then killed by immersion in hot water or by exposure to sunlight, steam, or the heat of an oven; much of the variety in the appearance of commercial cochineal is caused by the differing modes of treatment. It takes 70,000 insects to make one pound of cochineal. See also kermes.

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This article was most recently revised and updated by Amy Tikkanen.