Also called:
theobroma oil

cocoa butter, pale yellow, edible vegetable fat obtained from cocoa beans, having a mild chocolate flavour and aroma, and used in the manufacture of chocolate (including white chocolate), pharmaceutical products, and toiletries.

Cocoa butter is extracted from cocoa beans, which are the fatty seeds of the cacao tree (Theobroma cacao), a plant native to South and Central America. The Maya of Central America believed that the tree was sacred and that chocolate derived from the tree’s seeds was the food of the gods—which underlies the origin of the tree’s scientific name, theo meaning “god” and broma meaning “food.” Cacao trees thrive in tropical zones near the Equator, where temperatures are warm and precipitation and humidity are ample; they grow best in areas with partial shade that are protected from the wind. Between 20 and 60 beans grow inside a single cacao pod, along with a white pulp; each bean is about 55 percent cocoa butter.

The process of extracting cocoa butter from the beans begins when the pods are harvested and then fermented for five to eight days; this method separates the mature beans from the pulp. The beans are then dried, cleaned, roasted, and cracked to begin separating the shells from the nibs, which consist of both cocoa solids and cocoa butter. In a technique known as winnowing, the shells are blown away from the nibs. The nibs then are ground into a mass known as cacao liquor, which is pressed to release the fatty pale yellow cocoa butter. Once the cocoa butter has been extracted, the remaining block of cocoa solids can be used to make cocoa powder.

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Cocoa butter has unique properties, owing to its fatty acid content, which consists of palmitic acid, stearic acid, and oleic acid, with a smaller amount of linoleic acid. This relatively simple fatty acid profile yields triacylglycerols (TAGs; also known as triglycerides), which are made up of three fatty acids plus a glycerol molecule. At room temperature, 70 percent of TAGs in cocoa butter are solid, which gives chocolate its characteristic snap, creamy mouthfeel, and shiny appearance. The combination of fatty acids in the TAGs differs from region to region, and, therefore, depending on where the cacao was grown, the properties of cocoa butter may vary.

TAG molecules may form as many as six different crystal structures; this polymorphism can affect the melting behaviour of the cocoa butter. Depending on the specific crystal structure, the fat in cocoa butter melts at around 27 to 35 °C (about 81 to 95 °F), and it is solid at room temperature (25 °C [77 °F]). Therefore, it can be molded easily and will hold its shape when cooled. When eaten, however, it dissolves, making it ideal for candy. Cocoa butter can reach temperatures near 204.4 °C (400 °F) without burning; high temperatures destroy the cocoa flavour, rendering cocoa butter applicable for savory dishes.

Cocoa butter is stable, with a shelf life of two to five years, due to its antioxidant properties, and cocoa butter can increase the stability of other fats when combined with them. In addition, it contains choline, vitamin E, vitamin K, and oleic acid, which are healthy nutrients. It is, however, calorie dense, with all of its calories coming from fat. The properties of cocoa butter make it valuable for use in products such as soaps, lotions, cosmetics, and lip balm. Cocoa butter’s fatty acids soothe and hydrate dry skin, which can help relieve symptoms of dermatitis.

Being in relatively short supply and potentially costly to produce, cocoa butter is expensive. Although cacao is grown not only in South and Central America but in other regions as well, the cocoa butter extracted from available beans is insufficient to meet demand. In addition, about 30 percent of cacao crops are lost to damage from insects and disease. Climate change can further affect the quantity of beans produced and harvested each year.

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The high demand for cocoa butter has fueled the production of substitutes, most of them plant extracts. These fats, which include palm oil, soybean oil, and shea butter, are generally less expensive than cocoa butter. However, while they are similar in chemical structure to cocoa butter, their properties can differ.

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chocolate, food product made from cocoa beans, consumed as candy and used to make beverages and to flavour or coat various confections and bakery products. Rich in carbohydrates, it has several health benefits and is an excellent source of quick energy. It also contains minute amounts of the stimulating alkaloids caffeine and theobromine, which is highly toxic to dogs.

History of chocolate

The cacao tree was cultivated more than 3,000 years ago by the Maya, Toltec, and Aztec peoples, who prepared a beverage from its fruit, the cocoa bean (sometimes using it as a ceremonial drink) and also used the bean as a currency. The Maya considered chocolate to be the food of the gods, held the cacao tree to be sacred, and even buried dignitaries with bowls of the substance (along with other items deemed useful in the afterlife). In fact, the identification of the (Olmec-originated) word ka-ka-w (“cacao”) inscribed on those containers was key to deciphering the Maya’s phonetic manner of writing.

Spain was the earliest European country to incorporate chocolate into its cuisine, but exactly how that happened is vague. It is known that Christopher Columbus took cocoa beans to Spain after his fourth voyage in 1502, though little was made of it at that time. It has been commonly thought (though there appears to be no evidence) that in 1519 Montezuma II, the Aztec ruler of Mexico, served a bitter cocoa-bean drink to the Spanish conquistador Hernán Cortés, who subsequently introduced the drink to Spain. A strong possibility is that chocolate first arrived in Spain in 1544 with representatives of the Kekchí Mayan people of Guatemala, who came bearing gifts (including chocolate) to visit the court of Prince Philip. However, it was not until 1585 that the first recorded shipment of cocoa beans arrived in Spain from Veracruz, Mexico. Sweetened and flavoured with cinnamon and vanilla, chocolate was served as a hot beverage and became quite popular in the Spanish court. It was many years before chocolate had its introduction to France, England, and beyond.

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In 1657 a Frenchman opened a shop in London at which solid chocolate for making the beverage could be purchased at 10 to 15 shillings per pound. At that price only the wealthy could afford to drink it, and there appeared in London, Amsterdam, and other European capitals fashionable chocolate houses, some of which later developed into famous private clubs. In London many chocolate houses were used as political party meeting places as well as high-stakes gambling spots, notably Cocoa-Tree Chocolate-House (later the Cocoa-Tree Club), which opened in 1698, and White’s, which was opened by Francis White in 1693 as White’s Chocolate-House. About 1700 the English improved chocolate by the addition of milk. The reduction of the cost of the beverage was hampered in Great Britain by the imposition of high import duties on the raw cocoa bean, and it was not until the mid-19th century, when the duty was lowered to a uniform rate of one penny per pound, that chocolate became popular.

Meanwhile, the making of chocolate spread overseas and grew in sophistication. Chocolate manufacture started in the American colonies in 1765 at Dorchester, Massachusetts, using beans brought in by New England sea captains from their voyages to the West Indies. James Baker financed the first mill, which was operated by an Irish immigrant, John Hanan. Waterpower was used for grinding the beans. In the Netherlands in 1828, C.J. van Houten patented a process for pressing much of the fat, or cocoa butter, from ground and roasted cocoa beans and thus obtaining cocoa powder. In 1847 the English firm of Fry and Sons combined cocoa butter with chocolate liquor and sugar to produce sweet (eating) chocolate—the base of most chocolate confectionary—and in 1876 Daniel Peter of Switzerland added dried milk to make milk chocolate. The proliferation of flavoured, solid, and coated chocolate foods rapidly followed.

Production of chocolate

Chocolate is made from the kernels of fermented and roasted cocoa beans. The kernels are ground to form a pasty fluid chocolate liquor, which may be hardened in molds to form bitter (baking) chocolate, pressed to reduce the cocoa butter content and then pulverized to make cocoa powder, or mixed with sugar and additional cocoa butter to make sweet (eating) chocolate. The addition of dried or concentrated milk to sweet chocolate produces milk chocolate.

White chocolate, prized for its rich texture and delicate flavour, is technically not a chocolate. White chocolate is made from cocoa butter with added milk products, sugar, and flavourings such as vanilla.

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