When is air temperature the highest?

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On average, the time of day when air temperature is the highest is usually about 3 PM, as heat continues to build up after noon. However, after 3 PM the Sun is low enough in the sky for more heat to be lost than absorbed, causing a gradual decline in air temperature.

When do temperature inversions occur?

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Temperature inversions occur when the normal heat gradient of the atmosphere—air is warmer near the ground and cooler in the sky—is reversed. A temperature inversion typically occurs in the late evening and disappears just after sunrise. A visual cue that a temperature inversion has happened is fog (or smog in an urban environment).