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lithium aluminum hydride
chemical compound
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aldehydes
- In aldehyde: Oxidation-reduction reactions
…the most commonly used being lithium aluminum hydride (LiAlH4), sodium borohydride (NaBH4), or hydrogen (H2) in the presence of a transition catalyst such as nickel (Ni), palladium (Pd), platinum (Pt), or rhodium (Rh).
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carboxylic acids
- In carboxylic acid: Reduction
…reduction, the most important being lithium aluminum hydride (LiAlH4) and borane (BH3). The product is a primary alcohol (RCOOH → RCH2OH).
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properties
- In lithium: Chemical properties
…also is used to produce lithium aluminum hydride (LiAlH4), which quickly reduces aldehydes, ketones, and carboxylic esters to alcohols.
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reducing agent
- In aluminum: Compounds
Lithium aluminum hydride (LiAlH4), formed by the reaction of aluminum chloride with lithium hydride, is widely used in organic chemistry—e.g., to reduce aldehydes and ketones to primary and secondary alcohols, respectively.
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