If meteoritic material comes from specific regions of the asteroid belt, then the asteroids in such regions should have the chemical and mineralogical composition observed in the meteorites. The surface mineralogical composition of asteroids, in principle, can be determined directly by observations from Earth of the fraction of sunlight they reflect (albedo) and the spectrum of the reflected light (reflectance spectrum). A number of processes conspired, however, to make the association of certain asteroids with the various meteorite groups much more difficult than might be expected.
Although no two asteroidal reflectance spectra are exactly alike in detail, most asteroids fall into one of two general groups, the S class and the C class. S class asteroids (e.g., Gaspra and Ida, observed by the Galileo spacecraft, and Eros, visited by the NEAR Shoemaker spacecraft) have moderate albedos and contain mixtures of olivine, pyroxene, and metallic iron. These are the same minerals found in ordinary chondrites, but they also are present in a number of other meteorite types. The C class asteroids (e.g., Mathilde, observed by NEAR Shoemaker) have low albedos, and their more featureless spectra indicate the presence of light-absorbing materials, although at least half have a spectral feature associated with iron-bearing hydrous silicates. It is plausible to consider the C class asteroids as candidate sources for certain groups of carbonaceous chondrite meteorites. Their low albedos and spectral evidence of hydrous silicates, however, make them unlikely sources of ordinary chondrites.
When the S class asteroids were considered in more detail, there were difficulties in identifying them all as sources of ordinary chondrites. Largely because of their apparent range of mineralogies—specifically their ratios of olivine to pyroxene—the S class asteroids have been divided into seven subclasses. The asteroids in the S(IV) subclass seemed to have mineralogies that best matched those of the ordinary chondrites. This was supported by measurements made by an X-ray spectrometer on board NEAR Shoemaker of the elemental composition of the surface of Eros, an S(IV) asteroid. With the notable exception of a low sulfur content, the composition of Eros was found to be consistent with that of an ordinary chondrite. However, the spectra of the surfaces of S-class asteroids did not match those of ordinary chondrites. The discrepancy was resolved only in 2010 when the Japanese spacecraft Hayabusa returned to Earth from the S(IV) asteroid Itokawa with over 1,500 particles of dust that had surfaces characteristic of an S-class asteroid but on the inside were identical in composition to ordinary chondrites. The Hayabusa results showed that the surfaces of asteroids were changed by a set of processes collectively called space weathering that were responsible for both the low sulfur measurement of Eros and the mismatch between the spectra of chondrites and S-class asteroids.
Important component processes of space weathering are the impacts of meteorites and micrometeorites and the impingement of energetic solar wind particles, solar radiation, and galactic cosmic rays on surface materials. Over time these processes act to modify the chemical and physical surface properties of airless bodies such as Mercury, the Moon and some other planetary satellites, and asteroids and comets. Space weathering can be seen in comparisons of younger surfaces around craters with older terrains on Eros by NEAR Shoemaker and on Gaspra and Ida by Galileo.
Space weathering must also affect the spectra of the asteroidal sources of the other meteorite groups. Nevertheless, a number of more-or-less-convincing associations between groups of meteorites and types of asteroids have been made. It has been proposed that the CV and CO groups of carbonaceous chondrites come from the K class asteroids. As mentioned above, Vesta is the source of the howardite-eucrite-diogenite association, and a number of lines of evidence, including spectral measurements, point to Vesta’s being the source of the mesosiderites. The most likely source of the iron meteorites is the M class of asteroids, but enstatite chondrites and mesosiderites have also been linked to them. The pallasites may come from A class asteroids. For additional discussion of asteroid classes and their compositions, see asteroid: Composition.