If latex is allowed to evaporate naturally, the film of rubber that forms can be dried and pressed into usable articles such as bottles, shoes, and balls. South American Indians made such objects in early times: rubber balls, for instance, were used in an Aztec ceremonial game (called ollama) long before Christopher Columbus explored South America and the Caribbean. On his second voyage to the New World in 1493–96, Columbus is said to have seen natives in present-day Haiti play a game with balls made from the gum of a tree. In 1615 a Spaniard related how the Indians, having gathered the milk from incisions made in various trees, brushed it onto their cloaks and also obtained crude footwear and bottles by coating earthen molds and allowing them to dry.

The first serious accounts of rubber production and the primitive Native American system of manufacture were given in the 18th century by Charles-Marie de La Condamine, a member of a French geographic expedition sent to South America in 1735. La Condamine described “caoutchouc” (the French spelling of a native term for “weeping wood”) as the condensed juice of the Hevea tree, and in 1736 he sent rubber samples to Europe. Initially the new material was merely a scientific curiosity. Some years later the British scientist Joseph Priestley remarked on its usefulness for rubbing pencil marks from paper, and so the popular term rubber was coined. Other applications gradually developed, notably for waterproofing shoes and clothing.

Important progress toward a true rubber industry came at the beginning of the 19th century from the separate experiments of a Scottish chemist, Charles Macintosh, and an English inventor, Thomas Hancock. Macintosh’s contribution was the rediscovery, in 1823, of coal-tar naphtha as a cheap and effective solvent. He placed a solution of rubber and naphtha between two fabrics and in so doing avoided the sticky surfaces that had been common in earlier single-texture garments treated with rubber. Manufacture of these double-textured waterproof cloaks, henceforth known as “mackintoshes,” began soon afterward.

The work of Hancock, who became Macintosh’s colleague and partner, is of even greater importance. He first attempted to dissolve the rubber in turpentine, but his hand-coated fabrics were unsatisfactory in surface texture and smell. He then turned to the production of elastic thread. Strips of rubber were cut from the imported lumps and applied in their crude state to clothing and footwear. In 1820, in an effort to find a use for his waste cuttings, Hancock invented a masticator. Constructed of a hollow wooden cylinder equipped with teeth in which a hand-driven spiked roller was turned, this tiny machine, originally taking a charge of two ounces of rubber, exceeded Hancock’s greatest hopes. Instead of tearing the rubber to shreds, it produced enough friction to weld the scraps of rubber into a coherent mass that could be applied in further manufacture.

Macintosh’s and Hancock’s efforts resolved the initial problem of handling the raw material, but there remained one principal obstacle to the full exploitation of natural rubber: it softened with heat and hardened with cold (particularly annoying in North America, where the climate was more extreme than in Britain). It also was tacky, odorous, and perishable. These fundamental weaknesses were removed by the invention of vulcanization in 1839 by Charles Goodyear. Developing a compound of rubber, white lead, and sulfur and a heat treatment (or curing) process, Goodyear created a product—at first called fireproof gum, afterward vulcanized rubber—that exhibited impressive durability.

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Vulcanization made the modern rubber industry possible by permitting use of the substance in machinery and in tires for bicycles and, later, for automobiles. Though subsequent discoveries have refined Goodyear’s original techniques, the vulcanization process remains fundamentally the same as it was in his day. (For the chemical processes underlying vulcanization, see elastomer.)

With the advent of the bicycle and, somewhat later, the automobile and the invention of the solid and later the pneumatic rubber tire, demand for rubber grew rapidly. By 1900 more than 40,000 tons were used each year, about one-half from Brazil and one-half from Central Africa, where rubber was obtained principally from Landolphia vines. However, as an important industrial material, rubber was required in larger amounts than could easily be obtained from wild and widely dispersed trees in the Brazilian jungle or from African vines that produced only about one kilogram per hectare and were destroyed to obtain the rubber. With a view to cultivating rubber trees elsewhere, in 1876 seeds of the Hevea brasiliensis tree from the upper Orinoco basin were taken from Brazil to England at the instigation of the British India Office. Seedlings were raised at Kew Gardens and shipped to Ceylon (Sri Lanka) and Singapore. These trees were the origin of the rubber plantation industry in Asia, which now produces more than 90 percent of the world’s supply. The industry developed largely as a result of the work of Henry N. Ridley, director of the Singapore Botanic Gardens from 1888 until 1912. Ridley introduced horticultural and tapping methods that are still used today. Total world natural rubber production reached 3 million metric tons per year in the early 1970s, surpassed 4 million metric tons per year in the early 1980s, and reached 10 million metric tons per year in 2008. The principal rubber-producing countries are Thailand, Indonesia, and Malaysia, followed by the Asian producers China, India, the Philippines, Vietnam, and Sri Lanka and the West African states of Nigeria, Côte d’Ivoire, Cameroon, and Liberia.

The first decade of the 20th century saw the establishment of the motorcar in Europe and North America, and the automotive industry remained entirely dependent on natural rubber for its tires and other components until World War II. After Japan entered the war in 1941, Asian sources, except for Sri Lanka, were cut off from the Allies. In response, the United States and the Soviet Union attempted to cultivate alternative sources of natural rubber, such as the guayule shrub and the Russian dandelion. These attempts met with little success, but far better results were obtained from synthetic rubber. The United States in particular developed a synthetic rubber industry almost overnight, achieving a production of 800,000 tons per year. At the war’s end, with natural rubber again available, the U.S. synthetic rubber industry went into a sharp decline, but by the early 1950s superior and more uniform synthetics had become available. The export of these materials stimulated development of a synthetic rubber industry in Europe. In the early 1960s production of natural rubber was surpassed by that of synthetic elastomers.