Petroleum operations have been high-risk ventures since their inception, and several instances of notable damage to life and property have resulted from oil spills and other petroleum-related accidents as well as acts of sabotage. One of the earliest known incidents was the 1907 Echo Lake fire in downtown Los Angeles, which started when a ruptured oil tank caught fire. Other incidents include the 1978 Amoco Cadiz tanker spill off the coast of Brittany, the opening and ignition of oil wells in 1991 in Iraq and Kuwait during the Persian Gulf War, the 1989 Exxon Valdez spill off the Alaskan coast, and the 2010 Deepwater Horizon oil spill in the Gulf of Mexico. Accidents occur throughout the petroleum production value chain both onshore and offshore. The main causes of these accidents are poor communications, improperly trained workers, failure to enforce safety policies, improper equipment, and rule-based (rather than risk-based) management. These conditions set the stage for oil blowouts (sudden escapes from a well), equipment failures, personal injuries, and deaths of people and wildlife. Preventing accidents requires appreciation and understanding of the risks during each part of petroleum operations.

Human behaviours are the focus for regulatory and legislative health and safety measures. Worker training is designed to cover individual welfare as well as the requirements for processes involving interaction with others—such as lifting and the management of pressure and explosives and other hazardous materials. Licensing is a requirement for many engineers, field equipment operators, and various service providers. For example, offshore crane operators must acquire regulated training and hands-on experience before qualification is granted. However, there are no global standards followed by all countries, states, or provinces. Therefore, it is the responsibility of the operator to seek out and thoroughly understand the local regulations prior to starting operations. The perception that compliance with company standards set within the home country will enable the company to meet all international requirements is incorrect. To facilitate full compliance, employing local staff with detailed knowledge of the local regulations and how they are applied gives confidence to both the visiting company and the enforcing authorities that the operating plans are well prepared.

State-of-the-art operations utilize digital management to remove people from the hazards of surface production processes. This approach, commonly termed “digital oil field (DOF),” essentially allows remote operations by using automated surveillance and control. From a central control room, DOF engineers and operators monitor, evaluate, and respond in advance of issues. This work includes remotely testing or adjusting wells and stopping or starting wells, component valves, fluid separators, pumps, and compressors. Accountability is delegated from the field manager to the process owner, who is typically a leader of a team that is responsible for a specific process, such as drilling, water handling, or well completions. Adopting DOF practices reduces the chances of accidents occurring either on-site or in transit from a well.

Safety during production operations is considered from the bottom of the producing well to the pipeline surface transfer point. Below the surface, wells are controlled by blowout preventers, which the control room or personnel at the well site can use to shut down production when abnormal pressures indicate well integrity or producing zone issues. Remote surveillance using continuous fibre, bottom hole temperature and pressures, and/or microseismic indicators gives operators early warning signs so that, in most situations, they can take corrective action prior to actuating the blowout preventers. In the case of the 2010 Deepwater Horizon oil spill, the combination of faulty cement installation, mistakes made by managers and crew, and damage to a section of drill pipe that prevented the safety equipment from operating effectively resulted in a blowout that released more than 130 million gallons (about 4.1 million barrels) of oil into the Gulf of Mexico.

Transporting petroleum from the wellhead to the transfer point involves safe handling of the product and monitoring at surface facilities and in the pipeline. Production facilities separate oil, gas, and water and also discard sediments or other undesirable components in preparation for pipeline or tanker transport to the transfer point. Routine maintenance and downtime are scheduled to minimize delays and keep equipment working efficiently. Efficiencies related to rotating equipment performance, for example, are automated to check for declines that may indicate a need for maintenance. Utilization (the ratio of production to total capacity) is checked along with separator and well-test quality to ensure that the range of acceptable performance is met. Sensors attached to pipelines permit remote monitoring and control of pipeline integrity and flow. For example, engineers can remotely regulate the flow of glycol inside pipelines that are building up with hydrates (solid gas crystals formed under low temperatures and pressure). In addition, engineers monitoring sensing equipment can identify potential leaks from corrosion by examining light-scattering data or electric conductivity, and shutdown valves divert flow when leaks are detected. The oldest technique to prevent buildup and corrosion involves using a mechanical device called a “pig,” a plastic disk that is run through the pipeline to ream the pipe back to normal operational condition. Another type of pig is the smart pig, which is used to detect problems in the pipeline without shutting down pipeline operations.

With respect to the environment, master operating plans include provisions to minimize waste, including greenhouse gas emissions that may affect climate. Reducing greenhouse gas emissions is part of most operators’ plans, which are designed to prevent the emission of flare gas during oil production by sequestering the gas in existing depleted reservoirs and cleaning and reinjecting it into producing reservoirs as an enhanced recovery mechanism. These operations help both the operator and the environment by assisting oil production operations and improving the quality of life for nearby communities.

The final phase in the life of a producing field is abandonment. Wells and producing facilities are scheduled for abandonment only after multiple reviews by management, operations, and engineering departments and by regulatory agencies. Wells are selected for abandonment if their well bores are collapsing or otherwise unsafe. Typically, these wells are plugged with packers that seal off open reservoir zones from their connections with freshwater zones or the surface. In some cases the sections of the wells that span formerly producing zones are cemented but not totally abandoned. This is typical for fields involved in continued production or intended for expansion into new areas. In the case of well abandonment, a workover rig is brought to the field to pull up salvageable materials, such as production tubing, liners, screens, casing, and the wellhead. The workover rig is often a smaller version of a drilling rig, but it is more mobile and constructed without the rotary head. Aside from being involved in the process of well abandonment, workover rigs can be used to reopen producing wells whose downhole systems have failed and pumps or wells that require chemical or mechanical treatments to reinvigorate their producing zones. Upon abandonment, the workover rig is demobilized, all surface connections are removed, and the well site is reconditioned according to its local environment. In most countries, regulatory representatives review and approve abandonments and confirm that the well and the well site are safely closed.

Ben H. Caudle Priscilla G. McLeroy The Editors of Encyclopaedia Britannica
Top Questions

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petroleum, complex mixture of hydrocarbons that occur in Earth in liquid, gaseous, or solid form. A natural resource, petroleum is most often conceived of in its liquid form, commonly called crude oil, but, as a technical term, petroleum also refers to natural gas and the viscous or solid form known as bitumen, which is found in tar sands. The liquid and gaseous phases of petroleum constitute the most important of the primary fossil fuels.

Liquid and gaseous hydrocarbons are so intimately associated in nature that it has become customary to shorten the expression “petroleum and natural gas” to “petroleum” when referring to both. The first use of the word petroleum (literally “rock oil” from the Latin petra, “rock” or “stone,” and oleum, “oil”) is often attributed to a treatise published in 1556 by the German mineralogist Georg Bauer, known as Georgius Agricola. However, there is evidence that it may have originated with Persian philosopher-scientist Avicenna some five centuries earlier.

The burning of all fossil fuels (coal and biomass included) releases large quantities of carbon dioxide (CO2) into the atmosphere. The CO2 molecules do not allow much of the long-wave solar radiation absorbed by Earth’s surface to reradiate from the surface and escape into space. The CO2 absorbs upward-propagating infrared radiation and reemits a portion of it downward, causing the lower atmosphere to remain warmer than it would otherwise be. This phenomenon has the effect of enhancing Earth’s natural greenhouse effect, producing what scientists refer to as anthropogenic (human-generated) global warming. There is substantial evidence that higher concentrations of CO2 and other greenhouse gases have contributed greatly to the increase of Earth’s near-surface mean temperature since 1950.

History of use

Exploitation of surface seeps

Small surface occurrences of petroleum in the form of natural gas and oil seeps have been known from early times. The ancient Sumerians, Assyrians, and Babylonians used crude oil, bitumen, and asphalt (“pitch”) collected from large seeps at Tuttul (modern-day Hīt) on the Euphrates for many purposes more than 5,000 years ago. Liquid oil was first used as a medicine by the ancient Egyptians, presumably as a wound dressing, liniment, and laxative. The Assyrians used bitumen as a means of punishment by pouring it over the heads of lawbreakers.

Oil products were valued as weapons of war in the ancient world. The Persians used incendiary arrows wrapped in oil-soaked fibres at the siege of Athens in 480 bce. Early in the Common Era the Arabs and Persians distilled crude oil to obtain flammable products for military purposes. Probably as a result of the Arab invasion of Spain, the industrial art of distillation into illuminants became available in western Europe by the 12th century.

Several centuries later, Spanish explorers discovered oil seeps in present-day Cuba, Mexico, Bolivia, and Peru. Oil seeps were plentiful in North America and were also noted by early explorers in what are now New York and Pennsylvania, where American Indians were reported to have used the oil for medicinal purposes.

Extraction from underground reservoirs

Until the beginning of the 19th century, illumination in the United States and in many other countries was little improved over that which was known during the times of the Mesopotamians, Greeks, and Romans. Greek and Roman lamps and light sources often relied on the oils produced by animals (such as fish and birds) and plants (such as olive, sesame, and nuts). Timber was also ignited to produce illumination. Since timber was scarce in Mesopotamia, “rock asphalt” (sandstone or limestone infused with bitumen or petroleum residue) was mined and combined with sand and fibres for use in supplementing building materials. The need for better illumination that accompanied the increasing development of urban centres made it necessary to search for new sources of oil, especially since whales, which had long provided fuel for lamps, were becoming harder and harder to find. By the mid-19th century kerosene, or coal oil, derived from coal was in common use in both North America and Europe.

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The Industrial Revolution brought an ever-growing demand for a cheaper and more convenient source of lubricants as well as of illuminating oil. It also required better sources of energy. Energy had previously been provided by human and animal muscle and later by the combustion of such solid fuels as wood, peat, and coal. These were collected with considerable effort and laboriously transported to the site where the energy source was needed. Liquid petroleum, on the other hand, was a more easily transportable source of energy. Oil was a much more concentrated and flexible form of fuel than anything previously available.

The stage was set for the first well specifically drilled for oil, a project undertaken by American entrepreneur Edwin L. Drake in northwestern Pennsylvania. The completion of the well in August 1859 established the groundwork for the petroleum industry and ushered in the closely associated modern industrial age. Within a short time, inexpensive oil from underground reservoirs was being processed at already existing coal oil refineries, and by the end of the century oil fields had been discovered in 14 states from New York to California and from Wyoming to Texas. During the same period, oil fields were found in Europe and East Asia as well.

Significance of petroleum in modern times

At the beginning of the 20th century, the Industrial Revolution had progressed to the extent that the use of refined oil for illuminants ceased to be of primary importance. The oil and gas industry became the major supplier of energy largely because of the advent of the internal-combustion engine, especially those in automobiles. Although oil constitutes a major petrochemical feedstock, its primary importance is as an energy source on which the world economy depends.

The significance of oil as a world energy source is difficult to overdramatize. The growth in energy production during the 20th century was unprecedented, and increasing oil production has been by far the major contributor to that growth. By the 21st century an immense and intricate value chain was moving approximately 100 million barrels of oil per day from producers to consumers. The production and consumption of oil is of vital importance to international relations and has frequently been a decisive factor in the determination of foreign policy. The position of a country in this system depends on its production capacity as related to its consumption. The possession of oil deposits is sometimes the determining factor between a rich and a poor country. For any country, the presence or absence of oil has major economic consequences.

On a timescale within the span of prospective human history, the utilization of oil as a major source of energy will be a transitory affair lasting only a few centuries. Nonetheless, it will have been an affair of profound importance to world industrialization.

Properties of hydrocarbons

Chemical composition

Hydrocarbon content

Although oil consists basically of compounds of only two elements, carbon and hydrogen, these elements form a large variety of complex molecular structures. Regardless of physical or chemical variations, however, almost all crude oil ranges from 82 to 87 percent carbon by weight and 12 to 15 percent hydrogen. The more-viscous bitumens generally vary from 80 to 85 percent carbon and from 8 to 11 percent hydrogen.

Crude oil is an organic compound divided primarily into alkenes with single-bond hydrocarbons of the form CnH2n+2 or aromatics having six-ring carbon-hydrogen bonds, C6H6. Most crude oils are grouped into mixtures of various and seemingly endless proportions. No two crude oils from different sources are completely identical.

The alkane paraffinic series of hydrocarbons, also called the methane (CH4) series, comprises the most common hydrocarbons in crude oil. The major constituents of gasoline are the paraffins that are liquid at normal temperatures but boil between 40 °C and 200 °C (100 °F and 400 °F). The residues obtained by refining lower-density paraffins are both plastic and solid paraffin waxes.

The naphthenic series has the general formula CnH2n and is a saturated closed-ring series. This series is an important part of all liquid refinery products, but it also forms most of the complex residues from the higher boiling-point ranges. For this reason, the series is generally heavier. The residue of the refining process is an asphalt, and the crude oils in which this series predominates are called asphalt-base crudes.

The aromatic series is an unsaturated closed-ring series. Its most common member, benzene (C6H6), is present in all crude oils, but the aromatics as a series generally constitute only a small percentage of most crudes.