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Soil is a thin veneer that forms a discontinuous cover on the land areas of the Earth. Its volume and its mass are small in comparison to the major geospheres, but it is of vast importance to man. Superficially it might be considered merely as comminuted (pulverized) and decomposed bedrock; however, this viewpoint takes into account only its inorganic components and completely neglects the complex of organic compounds, living organisms, water, and included gases that gives the soil its characteristic properties and its value as the abode of life. Comminuted bedrock alone is not soil in any real sense; the Antarctic continent, where not ice-covered, has a surface of comminuted bedrock, as does the Moon, but neither material can properly be termed soil.
Soils result from the weathering of rocks, and hence their composition might be expected to reflect the composition of the rocks from which they were formed. This is true only in a very broad sense, however. Environmental factors play an important part in soil formation. The same parent rock may give rise to very different soils under different conditions. Climate, topography, vegetation, biological activity, and time are all important factors in determining the nature of a soil. Climate is probably the most important of these, as can be demonstrated by contrasting the soils developed on the same rock type under tropical and temperate conditions. In general, the soil in the humid tropics will be different in texture and composition and much less fertile, as a result of the intense leaching brought about by high rainfall, high temperatures, and the almost complete removal of organic matter by microorganisms.
The complex of inorganic compounds, organic compounds, water, and air that makes up the soil is in a continual state of change. Water tends to dissolve and remove the relatively soluble elements such as calcium, magnesium, sodium, and potassium, and the comparatively insoluble elements—aluminum, iron, and silicon—are thereby relatively enriched in the soil. The enrichment of iron is frequently manifested by a red-brown or yellow-brown colour caused by an accumulation of iron oxides. The most reactive part of the soil is the complex of clay minerals and organic matter, which is largely responsible for its agronomic characteristics. True soil does not exist without the presence of colloidal and organic matter. The relative absence of soils in desert areas reflects the fact that chemical and physical weathering of rocks alone does not necessarily result in soil formation. Most soil processes are directly or indirectly biological in nature. Organisms and organic compounds produced by their vital activities or their decomposition are effective agents for dissolving and extracting many elements from the inorganic constituents of the soil, thereby making them available for plant growth.
Although soils do differ in composition, the range of variation in the major elements is rather small. Minor and trace elements may show considerably greater variability. The importance of certain trace elements in the soil for the healthy growth of plants, and through the plants, of the animals that graze on them, has become increasingly apparent in recent years. Most soils contain these trace elements in sufficient amounts, but when deficiencies are present, puzzling diseases appear, which in the past have rendered large areas of otherwise suitable land unavailable for farming. On a large area in the North Island of New Zealand, for example, although it grew satisfactory pasture, sheep and cattle failed to thrive and eventually died if not removed. As a result, much of this area was given over to afforestation. It was eventually discovered that cobalt, in the amount of a few parts per million, would completely eliminate the disease when applied in fertilizer or administered directly to the animals. The ultimate explanation is the need of animals (but not plants) for vitamin B12, which contains an atom of cobalt in its structure.
Occasionally, an excess of a specific element may have a deleterious effect on plant growth. Most obvious, of course, are the alkaline or saline soils of desert and coastal areas on which only an impoverished vegetation exists. Magnesium-rich soils are notably infertile; such soils develop on areas of ultrabasic igneous rocks consisting largely of olivine, (Mg,Fe)2SiO4, and the boundaries of these areas can frequently be readily mapped from aerial photographs by the marked change in vegetation. Sometimes plants take up available trace elements in amounts deleterious to animals grazing on them. A well-known example is Astragalus racemosus (locoweed), which in some areas of the western U.S. contains sufficient selenium to be poisonous to grazing animals.
The possible correlation between soil geochemistry and the geographical distribution of disease is thus a field of extreme significance which as yet has been insufficiently studied. The problem is a complex one, in large part because of the difficulty in isolating the numerous factors involved.
The hydrosphere
The hydrosphere is the discontinuous shell of water—fresh, salt, and solid—on the surface of the Earth. As such it comprises the oceans and the connecting seas and inlets, the lakes, rivers, and streams, the groundwater that feeds them, and the snow and ice cover of high altitudes and high latitudes. The mass of the ocean waters far outweighs the other parts of the hydrosphere. Goldschmidt estimated that there are 273 litres of water in all its forms for every square centimetre of the Earth’s surface made up as follows:
Seawater thus makes up over 98 percent of the total mass of the hydrosphere, and its composition (see Table) essentially can be taken as giving the average composition of the hydrosphere.
Composition of seawater
Research during the past century has demonstrated that the composition of seawater is essentially uniform and that the relative proportions of the various ions are practically constant. In the open ocean the salinity (approximately the total weight of dissolved solids per kilogram) averages about 35 parts per thousand, but may rise to 40 parts per thousand in regions such as the Red Sea and the Persian Gulf, where rainfall and inflow are low and evaporation high. Sodium chloride is the dominant compound of the salts in solution and comprises about three-quarters of the whole; the remainder consists largely of chlorides and sulfates of magnesium, calcium, and potassium.
Though many data on minor and trace elements in seawater (Table) are available, the interpretation of these data is subject to some uncertainties. The concentrations of these elements are probably more variable than for the major elements and may depend to some degree on the sampling location. This is particularly true for the elements that are utilized by marine organisms. Phosphorus is a good example; it is markedly depleted in surface and near-surface waters by biological activity, but it enriches the deeper parts of the ocean through the dissolution of dead organisms. Silica is brought into the ocean in large amounts in solution in river water, but most of it is soon removed to become the skeletal material of diatoms, radiolaria, and sponges.
Seawater also contains dissolved gases in variable amounts. Seawater of normal salinity at 0° C (32° F) in equilibrium with the atmosphere will contain about eight millilitres per litre of dissolved oxygen and 14 millilitres per litre of dissolved nitrogen. Dissolved nitrogen is essentially an inert constituent, but dissolved oxygen plays a fundamental role in the growth and decay of organisms and so varies greatly in concentration from place to place. In stagnant regions that are rich in decaying organic matter the water may be completely depleted in free oxygen, and a considerable concentration of hydrogen sulfide may be present. Much of the Black Sea below a depth of a few hundred metres is in this condition.
Another dissolved gas of prime importance for biological activity is carbon dioxide. The conditions controlling its concentration are quite complex, however, because in solution it can be present as free carbon dioxide, as undissociated carbonic acid, as carbonate ions, and as bicarbonate ions. The concentration of these ions will also be affected by biological activity and by the precipitation or dissolution of calcium carbonate.
Circulation of water through the hydrosphere
The circulation of water through the hydrosphere is controlled in large part by the reservoir effect of the oceans. Evaporation from the ocean surface is precipitated as rainfall. Of that falling on the land, some is directly re-evaporated, some is absorbed into the reservoir of groundwater, and some flows off directly into rivers and streams. The total annual rainfall on the Earth is estimated to be 123 × 1018 grams, and the total annual runoff to the oceans 32 × 1018 grams.
Even the purest rainfall contains some material in solution, not only dissolved gases but also nonvolatile material. Rainfall near seacoasts always contains some sodium chloride and small amounts of other marine salts, the concentration of which falls off generally with distance from the ocean. Rainfall in industrial regions may of course contain a variety of pollutants; in many areas it is essentially a dilute sulfuric acid solution. Such material may also be carried far beyond the place of origin; acid rainfall in the Scandinavian countries probably originates in part from England and Germany.
The runoff from the land contains additional material in solution, picked up during its circulation through the crustal rocks. River water averages about 120 parts per million dissolved solids, but the range is great, from about 10 parts per million up to several thousand parts per million. Commonly, the range is from 50 to 200 parts per million; contents greater than 200 parts per million are usually the result of human activities or of drainage from soils containing soluble salts, as in desert regions.
With an average content of 120 parts per million dissolved matter, the rivers of the world deliver 3.9 × 109 tons of material in solution to the sea each year. The average concentration of the important constituents (in parts per million) is: bicarbonate, 58.4; sulfate, 11.2; chloride, 7.8; nitrate, 1.0; calcium, 15.0; magnesium, 4.1; sodium, 6.3; potassium, 2.3; iron, 0.67; and silica, 13.1. Although these ten constituents account for most of the dissolved material, many other elements have been detected in river and lake waters.
Geochemical balance of seawater over time
The 3.9 × 109 tons carried annually in solution to the oceans are but a small fraction of the total amount of material in solution in the oceans. Nevertheless, when integrated over the whole of geological time, more than 4 × 109 years, it greatly exceeds the present material in solution. Some of the material, especially sodium chloride, is of course cyclical, being circulated from the oceans to the land as aerosols and incorporated in marine sedimentary rocks and ultimately in large part being returned to the oceans in runoff.
Goldschmidt made an interesting calculation on the geochemical balance in seawater. From the amount and composition of sedimentary rocks he estimated that erosion during geological time had amounted to about 160 kilograms of igneous rock per square centimetre of the Earth’s surface. Combining this figure with the amount of seawater per square centimetre, 273 kilograms, he derived a figure of 600 grams of igneous rock eroded per kilogram of seawater. Assuming this 600 grams had gone fully into solution (obviously a gross simplification but a limiting one), he drew up a balance sheet between the amounts of different elements potentially supplied to the oceans and the amounts actually present. Some of these figures are presented in the Table. Despite the imperfections of the method, the results are certainly significant in a qualitative sense. Some elements—chlorine, bromine, boron, and sulfur—are present in seawater in amounts far in excess of those that can have been derived by erosion. The source of these “superabundant” elements has probably been volcanism and related magmatic activity. Halides, sulfates, and borates are deposited by volcanic gases and carried in solution in hot springs. The relative depletion of fluorine with respect to chlorine in seawater can be ascribed to the precipitation of highly insoluble fluorine-bearing compounds, mainly apatite (calcium fluophosphate). Sodium clearly remains in solution to a much greater extent than potassium; the latter element reacts with sedimentary materials to form insoluble potassium-bearing silicates such as illite and glauconite, which have no sodium-bearing analogs. Calcium is removed from solution much more effectively than strontium, evidently because it is utilized by organisms. Goldschmidt pointed out that many highly poisonous elements, such as arsenic and selenium, have been potentially supplied in dangerous amounts. Their concentration remains very low, however, presumably because of efficient processes of removal as insoluble compounds. Adsorption on colloidal particles of clay and iron oxides is a likely process.
| Geochemical balance of some elements in seawater | |||
| element | potential amount supplied to oceans (g/ton) | amount present in seawater (g/ton) | percentage in solution |
| lithium | 39 | 0.17 | 0.4 |
| boron | 2 | 4.5 | 250 |
| fluorine | 540 | 1.3 | 0.2 |
| sodium | 16,980 | 10,800 | 64 |
| magnesium | 12,540 | 1,290 | 10 |
| phosphorus | 708 | 0.09 | 0.01 |
| sulfur | 312 | 904 | 290 |
| chlorine | 188 | 19,400 | 10,300 |
| potassium | 15,540 | 392 | 2.5 |
| calcium | 21,780 | 411 | 1.9 |
| arsenic | 3 | 0.003 | 0.1 |
| bromine | 0.97 | 67 | 6,900 |
| rubidium | 186 | 0.12 | 0.06 |
| strontium | 180 | 8.1 | 4.6 |
| iodine | 0.18 | 0.06 | 33 |
| cesium | 4 | 0.0003 | 0.008 |
| barium | 150 | 0.02 | 0.01 |
The geological and geochemical evidence indicates that the ocean waters are, and have been for a long time, in a steady state of essentially unchanging composition. The addition of material by runoff from the land is adjusted by reactions within the ocean waters or between the ocean waters and sedimentary materials whereby the concentrations of the individual elements remain essentially constant. How far back in geological time this steady state has persisted remains something of an open question. The existence of most forms of marine life from the Cambrian to the present indicates a uniformity of marine conditions over the past 600,000,000 years; how far back into the Precambrian this uniformity extended is more difficult to elucidate. The earlier discussion of Precambrian iron formations suggested the possibility of very different atmospheric composition some 2,000,000,000 years ago, and the considerable interdependence of atmospheric and oceanic composition indicates that this might have resulted in marked geochemical differences in the ocean waters.
