Tables that show the effect of temperature upon the saturation mixing ratio r_w are readily available. Humidity of the air at saturation is expressed more commonly, however, as vapour pressure. Thus, it is necessary to understand vapour pressure and in particular the gaseous nature of water vapour.

The pressure of the water vapour, which contributes to the pressure of the atmosphere, can be calculated from the absolute humidity d_v by the gas equation:in which R is the gas constant, T the absolute temperature, M_w the molecular weight of water, and e the water vapour pressure in millibars (mb).

Relative humidity can be defined as the ratio of the vapour pressure of a sample of air to the saturation pressure at the existing temperature. Further, the capacity for vapour and the effect of temperature can now be presented in the usual terms of saturation vapour pressure.

Within a pool of liquid water, some molecules are continually escaping from the liquid into the space above, while more and more vapour molecules return to the liquid as the concentration of vapour rises. Finally, equal numbers are escaping and returning; the vapour is then saturated, and its pressure is known as the saturation vapour pressure, e_w. If the liquid and vapour are warmed, relatively more molecules escape than return, and e_w rises. There is also a saturation pressure with respect to ice. The vapour pressure curve of water has the same form as the curves for many other substances. Its location is fixed, however, by the boiling point of 100 °C (212 °F), where the saturation vapour pressure of water vapour is 1,013 mb (1 standard atmosphere), the standard pressure of the atmosphere at sea level. The decrease of the boiling point with altitude can be calculated. For example, the saturation vapour pressure at 40 °C (104 °F) is 74 mb (0.07 standard atmosphere), and the standard atmospheric pressure near 18,000 metres (59,000 feet) above sea level is also 74 mb; thus, it is where water boils at 40° C.

The everyday response of relative humidity to temperature can be easily explained. On a summer morning, the temperature might be 15 °C (59 °F) and the relative humidity 100 percent. The vapour pressure would be 17 mb (0.02 standard atmosphere) and the mixing ratio about 11 parts per thousand (11 grams of water per kilogram of air by weight). During the day the air could warm to 25 °C (77 °F), while evaporation could add little water. At 25 °C the saturation pressure is fully 32 mb (0.03 standard atmosphere). If, however, little water has been added to the air, its vapour pressure will still be about 17 mb. Thus, with no change in vapour content, the relative humidity of the air has fallen from 100 to only 53 percent, illustrating why relative humidity does not identify air masses.

The meaning of dew-point temperature can be illustrated by a sample of air with a vapour pressure of 17 mb. If an object at 15 °C is brought into the air, dew will form on the object. Hence, 15 °C is the dew-point temperature of the air—i.e., the temperature at which the vapour present in a sample of air would just cause saturation or the temperature whose saturation vapour pressure equals the present vapour pressure in a sample of air. Below freezing, this index is called the frost point. There is a one-to-one correspondence between vapour pressure and dew point. The dew point has the virtue of being easily interpreted because it is the temperature at which a blade of grass or a pane of glass will become wet with dew from the air. Ideally, it is also the temperature of fog or cloud formation.

The clear meaning of dew point suggests a means of measuring humidity. A dew-point hygrometer was invented in 1751. For this instrument, cold water was added to water in a vessel until dew formed on the vessel, and the temperature of the vessel, the dew point, provided a direct index of humidity. The greatest use of the condensation hygrometer has been to measure humidity in the upper atmosphere, where a vapour pressure of less than a thousandth millibar makes other means impractical.

Another index of humidity, the saturation deficit, can also be understood by considering air with a vapour pressure of 17 mb. At 25 °C the air has (31 − 17), or 14, mb less vapour pressure than saturated vapour at the same temperature; that is, the saturation deficit is 14 mb (0.01 standard atmosphere).

The saturation deficit has the particular utility of being proportional to the evaporation capability of the air. The saturation deficit can be expressed as and, because the saturation vapour pressure e_w rises with rising temperature, the same relative humidity will correspond to a greater saturation deficit and evaporation at warm temperatures.

Humidity and climate

The small amount of water in atmospheric vapour, relative to water on Earth, belies its importance. Compared with one unit of water in the air, the seas contain at least 100,000 units, the great glaciers 1,500, the porous earth nearly 200, and the rivers and lakes 4 or 5. The effectiveness of the vapour in the air is magnified, however, by its role in transferring water from sea to land by the media of clouds and precipitation and that in absorbing radiation.

The vapour in the air is the invisible conductor that carries water from sea to land, making terrestrial life possible. Fresh water is distilled from the salt seas and carried over land by the wind. Water evaporates from vegetation, and rain falls on the sea too, but the sea is the bigger source, and rain that falls on land is most important to humans. The invisible vapour becomes visible near the surface as fog when the air cools to the dew point. The usual nocturnal cooling will produce fog patches in cool valleys. Or the vapour may move as a tropical air mass over cold land or sea, causing widespread and persistent fog, such as occurs over the Grand Banks off Newfoundland. The delivery of water by means of fog or dew is slight, however.

When air is lifted, it is carried to a region of lower pressure, where it will expand and cool as described by the gas equation. It may rise up a mountain slope or over the front of a cooler, denser air mass. If condensation nuclei are absent, the dew point may be exceeded by the cooling air, and the water vapour becomes supersaturated. If nuclei are present or if the temperature is very low, however, cloud droplets or ice crystals form, and the vapour is no longer in the invisible guise of atmospheric humidity.

The invisible vapour has another climatic role—namely, absorbing and emitting radiation. The temperature of Earth and its daily variation are determined by the balance between incoming and outgoing radiation. The wavelength of the incoming radiation from the Sun is mostly shorter than 3 μm (0.0001 inch). It is scarcely absorbed by water vapour, and its receipt depends largely upon cloud cover. The radiation exchanged between the atmosphere and Earth’s surface and the eventual loss to space is in the form of long waves. These long waves are strongly absorbed in the 3- to 8.5-μm band and in the greater than 11-μm range, where vapour is either partly or wholly opaque. As noted above, much of the radiation that is absorbed in the atmosphere is emitted back to Earth, and the surface receipt of long waves, primarily from water vapour and carbon dioxide in the atmosphere, is slightly more than twice the direct receipt of solar radiation at the surface. Thus, the invisible vapour in the atmosphere combines with clouds and the advection (horizontal movement) of air from different regions to control the surface temperature.

The world distribution of humidity can be portrayed for different uses by different indexes. To appraise the quantity of water carried by the entire atmosphere, the moisture in an air column above a given point on Earth is expressed as a depth of liquid water. It varies from 0.5 mm (0.02 inch) over the Himalayas and 2 mm (0.08 inch) over the poles in winter to 8 mm (0.3 inch) over the Sahara, 54 mm (2 inches) in the Amazon region, and 64 mm (2.5 inches) over India during the wet season. During summer the air over the United States transports 16 mm (0.6 inch) of water vapour over the Great Basin and 45 mm (1.8 inches) over Florida.

The humidity of the surface air may be mapped as vapour pressure, but a map of this variable looks much like that of temperature. Warm places are moist, and cool ones are dry; even in deserts the vapour pressure is normally 13 mb (0.01 standard atmosphere), whereas over the northern seas it is only about 4 mb (0.004 standard atmosphere). Certainly the moisture in materials in two such areas will be just the opposite, so relative humidity is a more widely useful index.