Corinth remained the leading exporter of Greek vases until about 550 bc, though mass production quickly led to a drop in quality. These later vases were decorated with unambitious and stereotyped groups of animal or human figures; there was little or no interest in narrative. By the late 7th century bc Athenian artists had adopted many of the stylistic features of Corinthian pots, as well as the black-figure technique. Files of animals became popular at Athens, but the artists always maintained an interest in the narrative scenes that had been so popular in the Proto-Attic style. The finest example of the marriage of Corinthian discipline and Attic invention is the François vase (in the Archaeological Museum in Florence), produced about 570 bc and exported to Etruria in Italy. Its surface is divided into horizontal friezes containing hundreds of carefully drawn, tiny figures showing episodes from Greek myth. The professionalism of the Attic masters, so clearly displayed on this and other contemporary vases, contrasted with the laziness of the Corinthian painters, and it is hardly surprising that the Attic products soon captured the foreign markets.

The first generation of Athenian painters after 500 bc concentrated on large-scale narrative scenes. One, Exekias, was fond of heroes. His superb draftsmanship and sense of the monumental was emphasized by exceedingly detailed use of incision to indicate the patterns on drapery, weapons, and anatomy. The Amasis Painter, on the other hand, preferred the wild cavortings of the wine god, Dionysus, and his band of drunken followers.

In general, many old conventions were retained. Men were still painted in black on the red ground of the vase; women had white skins. But some of the work of the Amasis Painter and his contemporaries used an outline technique for women and certain other figures, and it must soon have become obvious that the brush allowed greater freedom than the graver. By about 530 bc several painters took the momentous decision to dispense with the old black-figure technique entirely and show all their figures in outline, the details being indicated only with the brush. The background of the vase was now painted solid black and the figures stood out dramatically against this sombre field. This is called the red-figure technique, and, in the hands of artists such as Euthymides and Euphronius, the style rapidly gained ground. It had several advantages over black-figure. Incising the older decoration was painfully laborious, and it was almost impossible to vary the thickness or intensity of the incised lines. The painted line, however, could be made thicker or thinner depending on the amount of pressure applied and the amount of paint on the brush; it could also be made lighter by diluting the glaze. Red-figure artists took advantage of all these tricks and found that it was possible to depict complicated groups of overlapping figures or incidents involving violent action. Cities other than Athens and Corinth had studios producing black-figure vases; of these the most distinguished were in Sparta and eastern Greece. By the end of the Archaic period, however, only Athens was producing and exporting finely decorated pottery in any quantity.

It has always been assumed that vase painting in the Orientalizing and Archaic periods mirrored developments in monumental art, and to a certain extent this seems to be true. Not many paintings on monuments survive, but a sufficient number exist to give a general idea of their form and technique. Temple models of the late Geometric and Orientalizing periods are decorated in a way that suggests that temples had paintings on their walls; fragments of such paintings have actually been found at the temple of Poseidon at the Isthmus of Corinth. The earliest reasonably well-preserved temple decoration, however, comes from the temple of Apollo at Thermon, in central Greece, and dates from the later 7th century bc. The temple roof was decorated with a series of square terra-cotta frieze plaques, called metopes, bearing mythological scenes. Although there are several similarities to contemporary vases, there are also important differences: black-figure incision is confined to relatively minor details of drapery, and the figures themselves are drawn in outline, the women then being overpainted in white. Among vases of this period, only the brightly painted drinking cups from the island of Chios seem at all similar in technique. Other terra-cotta plaques painted in a similar, though more developed, style have been found in Italy at Caere (where they decorate the interior walls of a temple) and on the Acropolis, at Athens, indicating that there was probably a continuous tradition in this technique.

More important, because more numerous, are the many paintings on stucco. These are found in Italy and Asia Minor, as well as in Greece. They were painted by Greeks or artists working under intense Greek influence. At Pitsa, near Corinth, votive plaques covered in stucco and then painted have been found. There was a flourishing school of Greek painters who decorated tombs in the colonies of southern Italy. In Asia Minor, two tombs dating from the Late Archaic period have been found near Elmalı, in ancient Lycia (what is now southwestern Turkey). Although depicting scenes from the life of a Lycian prince, they were certainly painted by Greeks. With the exception of the plaque from Pitsa, a minor work, all these paintings come from provincial areas of the Greek world and probably do not represent the very finest of paintings then in existence, but many are highly competent pieces of work and they do give some idea of the state of monumental painting at the time. As on the vases, the greatest emphasis was on finely controlled line. Colours were applied in flat, undifferentiated masses, and there was no attempt at shading, perspective, or illusionistic treatment. At Karaburun, near Elmalı, variety was introduced by the use of finely detailed motifs on the clothing of the prince, an effect closer to the work of Exekias than to the practices of the early red-figure vase painters.