Lava flows

The root zone of volcanoes is found some 70 to 200 km (40 to 120 miles) below the surface of Earth. There, in Earth’s upper mantle, temperatures are high enough to melt rock and form magma. At these depths, magma is generally less dense than the solid rocks surrounding and overlying it, and so it rises toward the surface by the buoyant force of gravity. In some cases, as in the undersea zones where the tectonic plates of Earth’s crust are separating, magma may move directly up to the surface through fissures that reach as deep as the mantle. In other cases, it collects in large underground reservoirs known as magma chambers before erupting to the surface. Molten rock that reaches the surface is called lava.

Most magma formed by partial melting of the mantle is basaltic in composition, but, as it ascends, it assimilates silica, sodium, and potassium from the surrounding host rocks. Volcanic rocks found where magma erupts to the surface are classified into four major types, or “clans”—basalt, andesite, dacite, and rhyolite. These rocks are ranked, as can be seen in the table, mainly by their silica content, which ranges from approximately 50 percent for basalt to approximately 75 percent for rhyolite. As silica content increases, rock types generally become more viscous.

If the vast, unseen undersea lava flows of the oceanic ridge system are considered, lava flows are the most common products of Earth’s volcanoes. There are two major types of lava flow, referred to around the world by their Hawaiian names: pahoehoe, a more fluid flow with a smooth to ropy surface; and aa (or a’a), a more viscous flow whose surface is covered by thick, jumbled piles of loose, sharp blocks. Both types have the same chemical composition; the difference seems to be in the eruptive temperature and the speed of movement of the flow. As much as 99 percent of the island of Hawaii is composed of aa and pahoehoe flows. Indeed, Kilauea volcano has erupted continuously since 1983, its lava flows covering more than 100 square km (40 square miles) of land and adding more than 2 square km (0.8 square mile) to the island where the lava has poured into the ocean. In the Mediterranean region, Mount Etna has issued lava more than 150 times since its first recorded activity in 1500 bc.

Explosions

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Massive volcanic explosions are caused by the rapid expansion of gases, which in turn can be triggered by the sudden depressurization of a shallow hydrothermal system or gas-charged magma body or by the rapid mixing of magma with groundwater. The ash, cinders, hot fragments, and bombs thrown out in these explosions are the major products observed in volcanic eruptions around the world. These solid products are classified by size. Volcanic dust is the finest, usually about the consistency of flour. Volcanic ash is also fine but more gritty, with particles up to the size of grains of rice. Cinders, sometimes called scoriae, are the next in size; these coarse fragments can range from 2 mm (0.08 inch) up to about 64 mm (2.5 inches). Fragments larger than 64 mm are called either blocks or bombs. Volcanic blocks are usually older rock broken by the explosive opening of a new vent. Large blocks ejected in such explosions have been hurled as far as 20 km (12 miles) from the vent. Volcanic bombs, in contrast, are generally incandescent and soft during their flight. Some bombs take on strange, twisted shapes as they spin through the air. Others have a cracked and separated crust that has cooled and hardened in flight; they are called “breadcrust bombs.”

A directed blast in which one side of a volcanic cone fails, as happened at Mount St. Helens in the United States in 1980, can cause destruction over several hundred square kilometres on the failed flank of the volcano. This is especially true if the blast cloud is heavily laden with fragmental debris and becomes dense and fluidized. It then takes on characteristics similar to a pyroclastic flow.

Pyroclastic flows

Pyroclastic flows are the most dangerous and destructive aspect of explosive volcanism. Variously called nuées ardentes (“glowing clouds”), glowing avalanches, or ash flows, they occur in many sizes and types, but their common characteristic is a fluidized emulsion of volcanic particles, eruption gases, and entrapped air, resulting in a flow of sufficiently low viscosity to be very mobile and of sufficiently high density to hug the ground surface. A pyroclastic flow can pour over the lip of an erupting vent, or it may form when an ash column becomes too dense to continue rising and falls back to the ground. In major caldera collapses associated with explosive volcanoes (see below Calderas), huge pyroclastic flows may issue from the ring fractures as the caldera block subsides.

Pyroclastic flows can move at speeds up to 160 km (100 miles) per hour and have temperatures ranging from 100 to 700 °C (212 to 1,300 °F). They sweep away and incinerate nearly everything in their path. Smaller pyroclastic flows are often confined to valleys. Large pyroclastic flows may spread out as a blanket deposit across many hundreds or even thousands of square kilometres around a major caldera collapse. During the past two million years, the area around Yellowstone National Park in the western United States has undergone three major caldera collapses involving pyroclastic eruptions of 280 to 2,500 cubic km (67 to 600 cubic miles) of ash flows and ash falls.

Gas clouds

Even beyond the limit of explosive destruction, the hot, ash-laden gas clouds associated with an explosive eruption can scorch vegetation and kill animals and people by suffocation. Gas clouds emitted from fumaroles (volcanic gas vents) or from the sudden overturn of a crater lake may contain suffocating or poisonous gases such as carbon dioxide, carbon monoxide, hydrogen sulfide, and sulfur dioxide. At Lake Nyos, a crater lake in Cameroon, West Africa, more than 1,700 people were killed by a sudden release of carbon dioxide in August 1986. Scientists theorize that carbon dioxide of volcanic origin had been seeping into the lake, perhaps for centuries, and had accumulated in its deep layers. It is thought that some disturbance, such as a large landslide into the lake, could have triggered the outburst of gas, creating an effervescence that stirred the lake and started the degassing.

The most common volcanic gases are water vapour, carbon dioxide, sulfur dioxide, and hydrogen sulfide. Small quantities of other volatile elements and compounds also are present, such as hydrogen, helium, nitrogen, hydrogen chloride, hydrogen fluoride, and mercury. The specific gaseous compounds released from magma depend on the temperature, pressure, and overall composition of the volatile elements present. The amount of available oxygen is of critical importance in determining which volatile gases are present. When oxygen is lacking, methane, hydrogen, and hydrogen sulfide are chemically stable, but when hot volcanic gases mix with atmospheric gases, water vapour, carbon dioxide, and sulfur dioxide are stable.

Some volcanic gases are less soluble in magma than others and therefore separate at higher pressures. Studies at Kilauea in Hawaii indicate that carbon dioxide begins to separate from its parent magma at depths of about 40 km (25 miles), whereas most of the sulfur gases and water are not released until the magma has nearly reached the surface. Fumaroles near Halemaumau Crater at Kilauea’s summit are rich in carbon dioxide that leaks from the magma chamber located 3 to 4 km (1.9 to 2.5 miles) beneath the surface. Fumaroles on the rift zones of Kilauea, however, are richer in water vapour and sulfur because much of the carbon dioxide leaks away at the summit before the magma is intruded into the rift zones.